I don't know that I agree with the littlefinger choice, only because he is supposed to be a fairly young man. The ages of the characters in the book will obviously have to be adjusted so that certain characters who get married in the story (eg Sansa Stark) are at a more appropriate age for modern society. Still, I think Geoffrey Rush looks about 10 years too old (having grown up with Catelyn Stark and her sister).
Similarly, I picture Jon Snow being 18-20 for the purposes of the show. Henry Cavill could be a good choice, as long as they keep him looking young (as long as he's always clean shaven, it should be fine).
Other than those two points, I think those are perfect choices!
I think shooting is scheduled to begin in October, but I'm not going to swear to that. If they've announced a target for the air date, it's probably listed in one of the earlier links in this thread.